5263-56-9Relevant academic research and scientific papers
The Effect of Triphenylphosphine in the GoAgg(II) System.
Barton, Derek H. R.,Beviere, Stephane D.
, p. 5689 - 5692 (1993)
The usual formation of ketone and alcohol under GoAgg(II) conditions can be totally replaced by the formation of the corresponding mono-alkyl substituted derivatives by addition of PPh3 and alkali metal salts.
The Functionalization of Saturated Hydrocarbons. Part 26. Ionic Substitution Reactions in GoAggIV Chemistry: The Construction of C-N, C-S and C-C Bonds
Barton, Derek H. R.,Warinthorn, Chavasiri
, p. 47 - 60 (2007/10/02)
Utilization of the GoAggIV system in the presence of sodium azide, sodium nitrite, sodium thiocyanate, sodium disulfide and tetraethylammonium cyanide converts saturated hydrocarbons into the corresponding alkyl azides, nitroalkanes, alkyl thiocyanates, dialkyl disulfides and alkyl cyanides, respectively.Mechanistic studies suggest an Fe-centered ligand coupling reaction pathway.Key Words: Gif systems; Selective functionalization, Iron catalysts, C-N bond formation, C-S bond formation, C-C bond formation
