52635-97-9Relevant academic research and scientific papers
Chemical synthesis of aspidosperma alkaloids inspired by the reverse of the biosynthesis of the rhazinilam family of natural products
McMurray, Lindsay,Beck, Elizabeth M.,Gaunt, Matthew J.
supporting information, p. 9288 - 9291 (2012/10/30)
Pyrrole reduction: Iterative metal-catalyzed C-H functionalization reactions facilitated the preparation of a highly substituted pyrrole derivative. This derivative could be transformed into the pyrrole-containing secondary metabolite, rhazinilam, which could in turn be transformed through a reductive transannular cascade process into the structurally complex pyrrolidine-containing alkaloid natural product, aspidospermidine.
