52645-01-9Relevant academic research and scientific papers
In situ generation of PhI+CF3 and transition-metal-free oxidative sp2 C-H trifluoromethylation
Xu, Cong,Liu, Jingxin,Ming, Wenbo,Liu, Yingjie,Liu, Jun,Wang, Mang,Liu, Qun
, p. 9104 - 9109 (2013)
These things are sent to tri us: The introduction of CF3 units into organic molecules is important and requires the development of convenient trifluoromethylating reagents. Here, PhI+CF3, an acyclic electrophilic "CF3
NEMATICIDE COMPOUNDS, COMPOSITIONS, AND METHODS OF THEIR MAKING AND USE
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Paragraph 0152; 0362; 0364; 0373, (2022/01/24)
The present application relates to compounds of formulae (I)-(VII) as defined herein, compositions containing these compounds, methods of their use, and methods of making. The compounds have nematacide activity.
Pd-Catalyzed C-S Activation/Isocyanide Insertion/Hydrogenation Enables a Selective Aerobic Oxidation/Cyclization
Chang, Jian,Liu, Bangyu,Yang, Yang,Wang, Mang
, p. 3984 - 3987 (2016/09/09)
Unique imidoylation of thioorganics with isocyanides endows an unprecedented aerobic oxidation process. Catalyzed by Pd(Ph3P)2Cl2 in the presence of Ph3SiH under N2 then upon exposure to air, a wide range of α-acyl ketene dithioacetals react with isocyanides to afford 5-hydroxy-α,β-unsaturated γ-lactams via a C-S bond activation, isocyanide migratory insertion, hydrogenation, selective aerobic oxidation, and intramolecular nucleophilic addition sequence.
