52648-04-1

Basic information

• Product Name: 1-BROMO-6-METHYLHEPTANE
• Synonyms: 1-BROMO-6-METHYLHEPTANE;6-Methylheptyl bromide;Heptane, 1-bromo-6-methyl-
• CAS NO: 52648-04-1
• Molecular Formula: C₈H₁₇Br
• Molecular Weight: 193.12
• Mol File: 52648-04-1.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 191.87°C (estimate)
• Flash Point: 56.1 °C
• Appearance: /
• Density: 1.1024 (estimate)
• Vapor Pressure: 0.739mmHg at 25°C
• Refractive Index: 1.4383 (estimate)
• Solubility: DCM, Hexanes
• CAS DataBase Reference: 1-BROMO-6-METHYLHEPTANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-BROMO-6-METHYLHEPTANE(52648-04-1)
• EPA Substance Registry System: 1-BROMO-6-METHYLHEPTANE(52648-04-1)

Safety Data

• Hazardous Substances Data: 52648-04-1(Hazardous Substances Data)

Usage

Uses

1-Bromo-6-methylheptane is a useful reagent for synthesis. It is an intermediate in the synthesis of Isononylphenol (I420140), a material used in the preparation method of UV/heat dual-curing blocked polyisocyanate emulsion.

InChI:InChI=1/C8H17Br/c1-8(2)6-4-3-5-7-9/h8H,3-7H2,1-2H3

Upstream product

• 1653-40-3 6-methylheptanol 
• 2519-37-1 methyl 6-methylheptanoate 
• 107-82-4 i-pentyl bromide 
• 7429-94-9 isohexylmagnesium bromide 
• 5392-57-4 6-methylheptane-1,6-diol 
• 626-88-0 1-bromo-5-methylpentane 
• 929627-19-0 toluene-4-sulfonic acid 6-methyl-heptyl ester 
• 211757-44-7 1,6-dibromo-6-methylheptane 

Downstream Products

• 110502-71-1 6-methylheptane-1-thiol 
• 35354-39-3 cis-2-Methyl-7-octadecen 
• 1388146-54-0 methyl 2,9-dimethyldecanoate 
• 1388146-74-4 2,9-dimethyldecanal 
• 1388146-79-9 methyl (Z)-4,11-dimethyldodec-2-enoate 
• 1388146-75-5 methyl (E)-4,11-dimethyldodec-2-enoate 
• 5129-55-5 9-methyldecanoic acid methyl ester 
• 119947-01-2 1-(6-methylheptyl)-1-cyclooctanone 
• 52648-05-2 (6-methyl-heptyl)-triphenyl-phosphonium; bromide 
• 74041-61-5 (3S,8S,9S,10R,14S,17R)-17-((S)-1,8-Dimethyl-nonyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-ol 
• 92038-33-0 10-methyl-4-oxoundecanoic acid 

Relevant articles and documents

MODIFIED AMINE LIPIDS

The disclosure provides ionizable amine lipids and salts thereof (e.g., pharmaceutically acceptable salts thereof) useful for the delivery of biologically active agents, for example delivering biologically active agents to cells to prepare engineered cells. The ionizable amine lipids disclosed herein are useful as ionizable lipids in the formulation of lipid nanoparticle-based compositions.

Regio- and stereochemical study of sex pheromone of pine sawfly; Diprion nipponica

Regio- and stereoisomers of 1,2,ω-trimethyldecyl propionate (ω = 5-9) were prepared from stereochemically pure chiral building blocks as sex pheromone candidates of a pine sawfly; Diprion nipponica. Among the synthesized candidates, (1S,2R,8S)-1,2,8-trimethyldecyl propionate was found to be the sex pheromone of D. nipponica, based on compatibility of its GC-MS data with that of the extract of females, and its significantly high pheromone activity in a field bioassay. The field bioassay of the synthesized compounds also revealed that (1S,2R,SR)-1,2,8-trimethyldecyl propionate, (1S,2R,7S)-1,2,7-trimethyldecyl propionate, and (1S,2R,6S)-1,2,6-trimethyldecyl propionate could attract male sawflies to some extent as pheromone mimics.

Structure-reactivity relationship in the reaction of highly reactive zinc with alkyl bromides

Zinc is different! Unlike with magnesium or lithium, the reactions of organic bromides with highly reactive zinc (Zn*) show sensitivity for the structure of the organic moiety. Selective insertions of Zn into tertiary C-Br bonds can be achieved [Eq. (a)]. Competitive kinetic techniques were used to quantify these findings.