5267-58-3Relevant academic research and scientific papers
Pentafluorophenyl carbonyl compounds in the Reformatsky-type reactions promoted with Fe(CO)5-based metal complex systems
Terent'ev,Vasil'eva,Chahovskaya,Mysova,Hambardzumyan,Kochetkov
, p. 669 - 673 (2008/12/22)
Iron pentacarbonyl is an effective promoter for additions of halogenated acid esters and nitriles to pentafluorophenyl carbonyl compounds 1, 4, and 5 by the Reformatsky-type reaction and reductive coupling of compound 1. The electron-withdrawing character
Addition of halocarboxylic acids esters and halohydrocarbons to pentafluorobenzaldehyde promoted by iron pentacarbonyl
Terent'ev,Vasil'eva,Chakhovskaya,Mysova,Kochetkov
, p. 1615 - 1618 (2007/10/03)
Iron pentacarbonyl is an efficient promoter of addition to the carbonyl group of pentafluorobenzene of alkyl α-halocarboxylates and alkyl halides. The electron-acceptor character of the pentafluorophenyl group essentially affects the course of reaction an
