52679-02-4Relevant academic research and scientific papers
Electrophilic Reactivities of Vinyl p-Quinone Methides
Eitzinger, Andreas,Mayer, Robert J.,Hampel, Nathalie,Mayer, Peter,Waser, Mario,Ofial, Armin R.
, p. 2182 - 2186 (2020)
The electrophilic reactivity of a series of 8-arylated vinyl p-quinone methides (pVQMs) was determined by analyzing the kinetics of their reactions with carbanions in DMSO at 20 °C according to the linear free energy relationship log k = sN(N + E). The electrophilicity parameters E for pVQMs were used to successfully predict Michael-additions with structurally diverse C-, N-, S-, and H-nucleophiles.
Tandem 1,6-addition/cyclization/vinylcyclopropane rearrangement at low temperature under metal-free conditions: an approach to spiro[4.5]cyclohexadienones
Yuan, Zhenbo,Gai, Kuo,Wu, Youzhi,Wu, Jie,Lin, Aijun,Yao, Hequan
supporting information, p. 3485 - 3488 (2017/03/30)
A tandem 1,6-addition/cyclization/vinylcyclopropane rearrangement reaction (VCPR) of vinylogous para-quinone methides at low temperature under metal-free conditions has been disclosed for the first time. This method provides an efficient strategy for the construction of a range of spiro[4.5]cyclohexadienones in good yield, exhibiting good functional group tolerance as well as gram-scale capacity.
Process for production of 2,6-di-tert-alkenyl phenols
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, (2008/06/13)
There is disclosed a process for the production of 2,6-di-tert-alkyl-4-alkenyl phenols wherein the improvement comprises the reaction of a 2,6-di-tert-alkyl phenol with an allyl halide to yield the 2,6-di-tert-alkyl-4-alkenyl phenol through the use of a triphase or polymer bound catalyst.
Certain cinnamyl phenols as growth inhibitors for mosquito larvae
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, (2008/06/13)
Poly-t-butyl-cinnamyl phenols and poly-t-butyl-dihydrocinnamyl phenols are disclosed to be useful for inhibiting the growth of mosquito larvae, thus providing means for controlling mosquito populations.
