52692-45-2

Basic information

• Product Name: Benzene, 1,1'-(1,1-dimethyl-1,4-butanediyl)bis-
• Synonyms: Benzene,1,1'-(1,1-dimethyl-1,4-butanediyl)bis
• CAS NO: 52692-45-2
• Molecular Formula: C18H22
• Molecular Weight: 238.373
• Mol File: 52692-45-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1,1-dimethyl-1,4-butanediyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1,1-dimethyl-1,4-butanediyl)bis-(52692-45-2)
• EPA Substance Registry System: Benzene, 1,1'-(1,1-dimethyl-1,4-butanediyl)bis-(52692-45-2)

Safety Data

• Hazardous Substances Data: 52692-45-2(Hazardous Substances Data)

Upstream product

• 100-41-4 ethylbenzene 
• 1985-57-5 2-methyl-2-phenylpentane 
• 17376-04-4 2-phenethyl iodide 
• 515-40-2 neophyl chloride 
• 122-78-1 phenylacetaldehyde 
• 563-47-3 3-Chloro-2-methylpropene 
• 71-43-2 benzene 

Relevant articles and documents

Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis

n-Alkyl arenes were prepared in a one-pot tandem dehydrogenation/olefin metathesis/hydrogenation sequence directly from alkanes and ethylbenzene. Excellent selectivity was observed when (tBuPCP)IrH2 was paired with tungsten monoaryloxide pyrrolide complexes such as W(NAr)(C 3H6)(pyr)(OHIPT) (1a) [Ar = 2,6-i-Pr2C 6H3; pyr = pyrrolide; OHIPT = 2,6-(2,4,6-i-Pr 3C6H2)2C6H3O]. Complex 1a was also especially active in n-octane self-metathesis, providing the highest product concentrations reported to date. The thermal stability of selected olefin metathesis catalysts allowed elevated temperatures and extended reaction times to be employed.