52703-70-5Relevant academic research and scientific papers
Preparation and Reactions of N-Phenacyl-N-tosylhydroxylamines and -hydrazines
Wessig, Pablo,Henning, Hans-Georg
, p. 983 - 986 (2007/10/02)
O-Alkyl-N-phenacyl-N-tosylhydroxylamines 3 were prepared in two steps from O-alkylhydroxylamines 1.In the presence of a base the N-tosylhydroxylamines 3 undergo rearrangement and cleavage to N-tosylphenacylamine (5) and aldehydes 6.N-Alkyl-N'-phenacyl-N,N'-ditosylhydrazines 12 were obtained by stepwise treating of N,N'-ditosylhydrazine with alkyl halide and phenacyl bromide/potassium tert-butoxide/DMF
