52735-51-0

Upstream product

• 126-81-8 dimedone 
• 108-98-5 thiophenol 
• 13271-49-3 3-bromo-5,5-dimethlycyclohex-2-en-1-one 
• 17530-69-7 3-chloro-5,5-dimethylcyclohex-2-en-1-one 

Downstream Products

• 82998-33-2 5,5-dimethyl-3-phenylsulfenyl-2-cyclohexenethione 
• 96530-11-9 VIa-p-nitrobenzoate 
• 1392815-09-6 5,5-dimethyl-4-(3-methyl-2-butenyl)-2-cyclohexen-1-one 
• 439868-85-6 3,3-dimethyl-4-(3-methylbut-2-en-1-yl)cyclohexan-1-one 
• 1422197-13-4 5,5-dimethyl-6-(3-methyl-2-butenyl)-3-(phenylsulfanyl)-2-cyclohexen-1-one 
• 52735-55-4 5,5-Dimethyl-3-phenylsulfonyl-2-cyclohexen-1-on 
• 36047-17-3 5,5-dimethyl-3-phenyl-2-cyclohexen-1-one 
• 72035-80-4 8b-Methoxy-2,2-dimethyl-3-phenylsulfanyl-1,2,2a,8b-tetrahydro-cyclobuta[a]naphthalene 
• 72035-76-8 (E)-7,7-Dimethyl-9-phenylsulfanyl-7,10-dihydro-6H-benzocycloocten-5-one 
• 72035-70-2 (E)-7,7-Dimethyl-9-phenylsulfanyl-7,8-dihydro-6H-benzocycloocten-5-one 
• 72035-99-5 1-(2-Methyl-allyl)-3-phenylsulfanyl-naphthalene 
• 72035-89-3 1-(2-Methyl-propenyl)-3-phenylsulfanyl-naphthalene 
• 900493-59-6 carbonic acid allyl ester 2,3,3-trimethyl-5-phenylsulfanyl-cyclohexa-1,5-dienyl ester 
• 56047-66-6 [3-Eth-(Z)-ylidene-5,5-dimethyl-cyclohex-1-enylsulfanyl]-benzene 

Relevant academic research and scientific papers

ANTICONVULSANT COMPOUNDS

The present application relates to compounds and methods for reducing the severity of convulsant activity or epileptic seizures, or for the treatment of chronic or acute pain.

An efficient FeCl3-catalyzed condensation of thiols with 1,3-dicarbonyl compounds under solvent-free conditions

A practical and environmentally friendly method has been developed for the synthesis of thiol-substituted cyclohex-2-enones using a FeCl 3-catalyzed condensation of cyclic 1,3-dicarbonyl compounds and aromatic/aliphatic thiols under solvent-fre

An approach toward the synthesis of PPAP natural product garsubellin A: Construction of the tricyclic core

In a study directed toward the bioactive natural product garsubellin A, an expedient route to the bicyclo[3.3.1]nonan-9-one bearing tricyclic core, with a bridgehead anchored tetrahydrofuran ring, is delineated. The approach emanating from commercially av

Asymmetric allylic alkylation of cyclic vinylogous esters and thioesters by Pd-catalyzed decarboxylation of enol carbonate and β-ketoester substrates

(Chemical Equation Presented) Excellent yields and enantioselectivities were achieved for the palladium-catalyzed asymmetric allylic alkylation of vinylogous thioesters. The close-to-neutral reaction conditions ensure that this reaction can tolerate a wide range of functionalities. Furthermore, this approach provides a convenient protocol for the synthesis of synthetically important α,α- and γ,γ-di-substituted cycloalkenones.

Reduction of Vinylogous Thioesters with Lithium Aluminum Hydride. I. Reduction of β-Phenylthio-α,β-unsaturated Cyclic Ketones

5,5,Dimethyl-3-phenoxy-2-cyclohexenone (Ib) was reduced with lithium aluminum hydride (LAH) to give the 1,2-addition product (IIIa). 2-Methyl-3-phenoxy-2-cyclopentetnone (IIa) gave a mixture of the allyl alcohol (IVa) and 1,2-addition product (IVb).On the