5276-61-9Relevant academic research and scientific papers
Facile and purification free synthesis of peptides utilizing ROMPgel- and ROMPsphere-supported coupling reagents
Barrett, Anthony G.M.,Bibal, Brigitte,Hopkins, Brian T.,K?bberling, Johannes,Love, Andrew C.,Tedeschi, Livio
, p. 12033 - 12041 (2007/10/03)
5-Norbornene-2-carboxaldehyde and norbornadiene were respectively converted into norbornene derivatives functionalized with fluoroformamidinium hexafluorophosphate and 2-bromo-N-methylpyridinium tetrafluoroborate residues. Both these norbornene monomers were ring opening metathesis polymerized or graft copolymerized onto polystyrene cores to produce ROMPgel and ROMPsphere peptide-coupling reagents. These were used to prepare hindered amides, dipeptides and tripeptides with minimal purification in parallel arrays.
