52855-87-5Relevant academic research and scientific papers
Coordination chemistry of ene-1,1-diamines and a prototype "carbodicarbene"
Fuerstner, Alois,Alcarazo, Manuel,Goddard, Richard,Lehmann, Christian W.
supporting information; scheme or table, p. 3210 - 3214 (2009/02/08)
(Chemical Equation Presented) Carbophilic Lewis acids can polarize a coordinated π-bond by a slippage mechanism. A series of stable ylid- or enolate gold complexes of ene-1,1-diamines not only emulate this property, but also reveal the exceptional donor capacity of such electron-rich olefin ligands. Moreover, the first metal complex of a tetraaminoallene is reported, which features a prototype "carbodicarbene" ligand bound to a transition-metal template.
