528577-33-5Relevant academic research and scientific papers
C-X (X=Br, I) bond-tolerant aerobic oxidative cross-coupling: A strategy to selectively construct β-aryl ketones and aldehydes
Chen, Mao,Wang, Jie,Chai, Ziyi,You, Cai,Lei, Aiwen
supporting information; experimental part, p. 341 - 346 (2012/05/04)
Using moelcular oxygen as the terminal oxidant, various aryl halide-containing β-aryl ketones and aldehydes can be synthesized directly from readily available allyic alcohols and boronic acids via palladium-catalyzed oxidative cross-coupling reactions. The dual roles of copper, including electron-carrier and Lewis acid functions, are supposed to be critical for the high reactivity and selectivity of this aerobic oxidative coupling transformation. Copyright
Synthesis of low generation phenylenealkylene dendrons as nonpolar building blocks for a dendrimer construction set
Beinhoff, Matthias,Karakaya, Birol,Schlüter, A. Dieter
, p. 79 - 90 (2007/10/03)
The gram scale syntheses of first and second generation (G1 and G2) dendrons 1-4, and 35, based on aryl and alkyl moieties, by Suzuki-Miyaura cross-coupling are presented. Both a divergent and an accelerated convergent route are applied. In addition, first results on the synthesis of hyperbranched oligomers of AB2 monomer 19 are reported.
