528861-64-5Relevant academic research and scientific papers
Conformational evaluation of some 4-deoxyhex-4-enopyranose derivatives and their use in the preparation of a previously undescribed class of 3-thio-L-sorbopyranosides and their 6-C-methoxy analogues
Capozzi, Giuseppe,Catelani, Giorgio,D'Andrea, Felicia,Menichetti, Stefano,Nativi, Cristina
, p. 123 - 132 (2003)
A new series of thio-substituted sugars were synthesised relying on the totally regio- and stereoselective cycloaddition of 4-deoxyhex-4-enopyranose derivatives to 'in situ' generated oxothiones. Conformational studies of the above unsaturated sugars showed a marked prevalence of the all-axial conformer.
