52887-04-4Relevant academic research and scientific papers
The Germanium-Carbon Bond Cleavage Reaction of (Germylmethyl)amine Derivatives. Mechanism and Stereochemistry
Terunuma, Daiyo,Masuo, Koujiro,Kizaki, Hiroaki,Nohira, Hiroyuki
, p. 160 - 164 (2007/10/02)
A facile cleavage reaction of the germanium-carbon bond of (germylmethyl)amine derivatives to give a germyl anion and an azomethine derivative was developed.The effects of substituents such as phenyl, benzyl, and ethyl groups on the germanium and nitrogen atoms of the (germylmethyl)amine derivatives on the cleavage reaction were investigated.The mechanism was also investigated based on the stereochemistry of the cleavage reaction using an optically active organogermanium compound.
Facile Cleavage of Ge-C Bonds of N-(Germylmethyl)benzylamine Derivatives. Generation of Germyl Anions
Terunuma, Daiyo,Kizaki, Hiroaki,Sato, Takashi,Masuo, Koujiro,Nohira, Hiroyuki
, p. 97 - 100 (2007/10/02)
The reactions of N-(germylmethyl)benzylamine derivatives with butyllithium were carried out.Facile cleavages of Ge-C bonds of the N-benzylgermylmethylamine derivatives giving the corresponding germyl anions and N-pentylbenzylamine were observed.The reacti
Photochemical Addition of Benzyltriethylgermane and Dibenzyldiethylgermane to Olefines
Kobayashi, Masanori,Yoshida, Masato,Kobayashi, Michio
, p. 3169 - 3174 (2007/10/02)
A novel photochemical addition of a germanyl radical to the olefinic double bond was discovered when benzyltriethylgermane or dibenzyldiethylgermane was irradiated with a medium-pressure mercury lamp in the presence of olefins.
