529474-85-9Relevant academic research and scientific papers
Studies on the regio- and stereoselectivity of halohydroxylation of 1,2-allenyl sulfides or selenides
Ma, Shengming,Hao, Xueshi,Meng, Xiaofeng,Huang, Xian
, p. 5720 - 5724 (2007/10/03)
It was observed that the halohydroxylation of 1,2-allenyl sulfides or selenides with Br2 (CuBr2 or NBS) or I2 and water demonstrated a fairly good regioselectivity (i.e., the C=C bond that is remote from the S or Se atom w
Reversed stereoselectivity in iodohydroxylation of allenyl sulfides. An efficient synthesis of (Z)-3-organosulfur-2-iodo-2-propenols
Ma, Shengming,Hao, Xueshi,Huang, Xian
, p. 1217 - 1219 (2007/10/03)
(Matrix presented) It is observed that the iodohydroxylation of 1, 2-allenyl sulfides with I2 and water in aqueous acetone showed Z-selectivity, which is opposite to that of the iodohydroxylation of 1, 2-allenyl sulfoxides.
