529477-58-5

Basic information

• Product Name: 2(3H)-Thiazolethione, 3-hydroxy-5-(4-methoxyphenyl)-4-methyl-
• CAS NO: 529477-58-5
• Molecular Formula: C11H11NO2S2
• Molecular Weight: 253.346
• Mol File: 529477-58-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2(3H)-Thiazolethione, 3-hydroxy-5-(4-methoxyphenyl)-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2(3H)-Thiazolethione, 3-hydroxy-5-(4-methoxyphenyl)-4-methyl-(529477-58-5)
• EPA Substance Registry System: 2(3H)-Thiazolethione, 3-hydroxy-5-(4-methoxyphenyl)-4-methyl-(529477-58-5)

Safety Data

• Hazardous Substances Data: 529477-58-5(Hazardous Substances Data)

Upstream product

• 1092775-94-4 1-(ethoxythiocarbonylsulfanyl)-1-(4-methoxyphenyl)-2-propanone oxime 

Downstream Products

• 948578-25-4 5-(p-methoxyphenyl)-4-methyl-3-(1-phenyl-1-methyleth-1-oxy)-thiazole-2(3H)-thione 
• 1222145-87-0 N-adamantylcarbonyloxy-4-methyl-5-(4-methoxyphenyl)thiazole-2(3H)-thione 
• 868273-81-8 N-benzoyloxy-4-methyl-5-(4-methoxyphenyl)thiazole-2(3H)-thione 
• 1222145-89-2 N-(4-methoxybenzoyl)-4-methyl-5-(4-methoxyphenyl)thiazole-2(3H)-thione 
• 1222145-81-4 N-decanoyloxy-4-methyl-5-(4-methoxyphenyl)thiazole-2(3H)-thione 
• 1222145-79-0 N-acetyloxy-4-methyl-5-(4-methoxyphenyl)thiazole-2(3H)-thione 
• 1222145-83-6 N-cyclohexylcarbonyloxy-4-methyl-5-(4-methoxyphenyl)thiazole-2(3H)-thione 
• 1415260-84-2 3-(1'-cyanonona-1',8'-dien-5'-oxy)-5-(p-methoxyphenyl)-4-methylthiazole-2(3H)-thione 
• 1415260-85-3 3-(1'-cyanonona-1',8'-dien-5'-oxy)-5-(p-methoxyphenyl)-4-methylthiazole-2(3H)-thione 
• 1415260-82-0 3-(1'-methoxynona-1',8'-dien-5'-oxy)-5-(p-methoxyphenyl)-4-methylthiazole-2(3H)-thione 
• 1415260-83-1 3-(1'-methoxynona-1',8'-dien-5'-oxy)-5-(p-methoxyphenyl)-4-methylthiazole-2(3H)-thione 
• 1415260-81-9 3-(9'-methyldeca-1',8'-dien-5'-oxy)-5-(p-methoxyphenyl)-4-methylthiazole-2(3H)-thione 
• 1293965-57-7 2-(2-methylpropyl-2-sulfanyl)-5-(4-methoxyphenyl)-4-methylthiazole N-oxide 
• 902757-40-8 3-(2-methylprop-2-oxy)-5-(4-methoxyphenyl)-4-methylthiazole-2(3H)-thione 

Relevant articles and documents

Spin trapping of alkoxyl radicals generated from 5-methyl and 5-aryl-3-alkoxy-4-methylthiazole-2(3H)-thiones in photochemically induced and microwave-initiated reactions

Methoxyl and isopropoxyl radicals were generated from N-alkoxy-4,5-dimethylthiazole-2(3H)-thiones (λmax～320 nm) and 5-aryl derivatives (aryl=p-XC6H4; X=MeO, H, AcNH, Cl) (λmax～335 nm) in photochemically and microwave-induced reactions. Alkoxyl radicals were trapped with dimethylpyrrolidine N-oxide and characterized as spin adducts via EPR. Cumyloxyl radicals were liberated in a similar manner from N-cumyloxy-5-(4-methoxyphenyl)-4-methylthiazole-2(3H)-thione. A noteworthy bathochromic shift was found for the lowest energy transition of N-(hydroxy)indeno[2,1-d]thiazole-2(3H)-thione (λmax=376 nm), if compared to the UV-vis absorption of N-hydroxy-4-methyl-5-phenylthiazole-2(3H)-thione (λmax=338 nm). Syntheses of alkoxyl radical precursors and procedures for conducting N,O-homolysis are described in a full account.