52963-10-7Relevant academic research and scientific papers
Stereospecific synthesis of highly substituted skipped dienes through multifunctional palladium catalysis
Thadani, Avinash N.,Rawal, Viresh H.
, p. 4317 - 4320 (2007/10/03)
(equation presented) Multifunctional palladium catalysis is utilized in the one-pot stereocontrolled synthesis of tetrasubstituted alkenes. The homogeneous palladium dihalide catalyst utilized for bromo-/chloroallylation of alkynes is then reused in situ
Palladium-Catalyzed Consecutive One-Pot Reaction of Acetylenes with Allyl Bromide and Organotin Compounds
Kosugi, Masanori,Sakaya, Takashi,Ogawa, Shinji,Migita, Toshihiko
, p. 3058 - 3061 (2007/10/02)
Allyl bromide adds to a terminal acetylene under the palladium complex to give 1-bromo-1,4-pentadiene which can further react with organotin compounds without further addition of palladium complex to give 1-substituted 1,4-pentadiene. These two reactions
