530158-75-9Relevant academic research and scientific papers
Palladium-catalyzed cascade ring expansion reaction of 1-(3-methoxycarbonyloxy-1-propynyl)cyclobutanols with phenols
Yoshida, Masahiro,Nemoto, Hideo,Ihara, Masataka
, p. 8583 - 8586 (1999)
A palladium-catalyzed transformation of 1-(3-methoxycarbonyloxy-1-propynyl)cyclobutanols to cyclopentanones on treatment with phenol derivatives is described. This process can be visualized to proceed via nucleophilic attack to allenyl palladium species b
Palladium-catalysed cascade ring expansion reaction of cyclobutanols that have a propargylic moiety with nucleophiles
Yoshida, Masahiro,Komatsuzaki, Yuki,Nemoto, Hideo,Ihara, Masataka
, p. 3099 - 3107 (2007/10/03)
Cascade ring rearrangement of four-membered ring systems containing various propargylic components by a palladium catalyst is described. The reactions of cyclobutanols that have a propargylic carbonate moiety with phenols as nucleophiles produce phenoxy-i
A novel methodology for the synthesis of cyclic carbonates based on the palladium-catalyzed cascade reaction of 4-methoxycarbonyloxy-2-butyn-1-ols with phenols, involving a novel carbon dioxide elimination-fixation process
Yoshida, Masahiro,Fujita, Mika,Ishii, Tooru,Ihara, Masataka
, p. 4874 - 4881 (2007/10/03)
A palladium-catalyzed CO2-recycling reaction has been developed. Reaction of 4-methoxycarbonyloxy-2-butyn-1-ols with phenols, carried out in the presence of a palladium catalyst, produces phenoxy-substituted cyclic carbonates by way of a pathwa
