530159-02-5

Basic information

• Product Name: [((NC₅H₄)N₂C₄H₈CH₂P(C₆H₅)2)2PtCl]⁽¹⁺⁾*ClO₄^(1-)
• CAS NO: 530159-02-5
• Molecular Weight: 1052.84
• Mol File: 530159-02-5.mol

Chemical Properties

• CAS DataBase Reference: [((NC₅H₄)N₂C₄H₈CH₂P(C₆H₅)2)2PtCl]⁽¹⁺⁾*ClO₄^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: [((NC₅H₄)N₂C₄H₈CH₂P(C₆H₅)2)2PtCl]⁽¹⁺⁾*ClO₄^(1-)(530159-02-5)
• EPA Substance Registry System: [((NC₅H₄)N₂C₄H₈CH₂P(C₆H₅)2)2PtCl]⁽¹⁺⁾*ClO₄^(1-)(530159-02-5)

Safety Data

• Hazardous Substances Data: 530159-02-5(Hazardous Substances Data)

Upstream product

• 216436-87-2 1-[(diphenylphosphino)methyl]-4-(2-pyridyl)piperazine 

Relevant articles and documents

Platinum complexes of tertiary amine functionalised phosphines

The reaction of several tertiary amine functionalised phosphines with [Pt(COD)Cl2] has been studied. Reactions with ratios of L:Pt = 2 proceeded cleanly to give either cis or trans complexes depending on the cone angle of the phosphines. The trans complexes could also be prepared by reaction with Zeise's salt. Reactions of [Pt(COD)Cl2] with L:Pt = 1 are less straightforward, and a mixture of cis and trans monodentate complexes, and in one example, a chelate complex have been isolated. The X-ray crystal structures of [PtCl2(η2-iPr2PN(Me) CH2CH2NMe2)] and a monodentate complex [trans-PtCl2(η1-iPr2 PNH-c-NC5H10)2] are reported.