53016-36-7

Upstream product

• 138225-48-6 C₂₂H₄₁AlO₂ 
• 121811-23-2 <1S-(1α,3aβ,7aα)>-1-tert-butoxy-2,3,3a,6,7,7a-hexahydro-7a-methyl-5-trimethylsilyloxy-1H-indene 
• 138225-58-8 α-Chloro-β-(m-methoxyphenyl)ethylphenylsulfide 
• 138225-59-9 (1S,1'RS,3aS,4RS,7aS)-1-tert-Butoxy-4-(2'-m-methoxyphenyl-1'-phenylthioethyl)-7a-methyl-3a,4,7,7a-tetrahydro-5⁽⁶⁾-indan-5-one 

Downstream Products

• 65329-24-0 Acetic acid (1S,3aS,4S,8aS)-4-[2-(3-methoxy-phenyl)-ethyl]-8a-methyl-5-oxo-decahydro-azulen-1-yl ester 
• 65329-21-7 (1S,3aS,4S,8aS)-1-tert-Butoxy-4-[2-(3-methoxy-phenyl)-ethyl]-8a-methyl-octahydro-azulen-5-one 

Relevant academic research and scientific papers

ZINC(II)-CHLORIDE INDUCED THIOALKYLATION OF ALUMINIUM ENOLATES; ENANTIOSELECTIVE SYNTHESIS OF ESTRADIOL-3-METHYL-17-tert-BUTYL DIETHER

Zinc(II)-chloride induced thioalkylation of the aluminium enolate 6 generated by conjugate reduction of the enone 5 leads - directly or via its trimethylsilylenol ether 6 - to alkylated hydrindanones 10 which are important intermediates in the synthesis o

9,10-Seco-steroid preparation

A process for the preparation of 9,10-seco-steroids of the formula STR1 wherein R1 and R2 independently are hydrogen, amino, OR5, OCOR6 or NHCOR5 wherein R5 is hydrogen or lower alkyl and R

6,9-Oxido-9,10-secoestrane derivatives and method of synthesis

6,9-Oxido-9,10-seco-1,3,5(10),6,8,14-estrahexaenes, useful as intermediates in the total synthesis of steroids, of the formula SPC1 Wherein n is 1 or 2, R1 is lower-alkyl, R2, R3 and R4 are H, alkoxy or acyloxy,

Synthesis of A-ring aromatic steroids

Total synthesis of steroids of the estrone and equilenin series involving conjugate 1,4-addition of a meta-substituted benzyl organometallic reagent to a C/D bicyclic methylene ketone. An aromatization of the B-ring of Δ 9(11) estrone derivatives.