53067-10-0

Basic information

• Product Name: 3,7-dimethyloctane-1,6-diol
• Synonyms: 3,7-dimethyloctane-1,6-diol;3,7-Dimethyloctan-1,6-diol;3,7-Dimethyl-1,6-octanediol;1,6-Octanediol, 3,7-dimethyl-;Einecs 258-341-8
• CAS NO: 53067-10-0
• Molecular Formula: C10H22O2
• Molecular Weight: 174.28048
• EINECS: 258-341-8
• Mol File: 53067-10-0.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 263.6°Cat760mmHg
• Flash Point: 115.6°C
• Appearance: /
• Density: 0.918g/cm³
• Vapor Pressure: 0.00143mmHg at 25°C
• Refractive Index: 1.453
• CAS DataBase Reference: 3,7-dimethyloctane-1,6-diol(CAS DataBase Reference)
• NIST Chemistry Reference: 3,7-dimethyloctane-1,6-diol(53067-10-0)
• EPA Substance Registry System: 3,7-dimethyloctane-1,6-diol(53067-10-0)

Safety Data

• Hazardous Substances Data: 53067-10-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H22O2/c1-8(2)10(12)5-4-9(3)6-7-11/h8-12H,4-7H2,1-3H3

Upstream product

• 500-00-5 3-p-menthene 
• 61263-98-7 (+/-)-Methyl citronellate oxide 
• 499-54-7 (+/-)-7-isopropyl-4-methyl-1-oxepan-2-one 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 106-22-9 Citronellol 

Downstream Products

• 57020-54-9 6-hydroxy-3,7-dimethyloctan-1-al 
• 68330-67-6 (4R,7S)-4-methyl-7-(1-methylethyl)oxepan-2-one 
• 133267-37-5 (4S,7R)-(+)-4-methyl-7-iso-propyl-2-oxo-oxepanone 

Relevant articles and documents

Lactones 34 [1]. Application of alcohol dehydrogenase from horse liver (HLADH) in enantioselective synthesis of δ- and ε-lactones

The ability of horse liver alcohol dehydrogenase (HLADH) to the enantioselective oxidation of primary-primary, primary-secondary and primary-tertiary aliphatic 1,5- and 1,6-diols 1a-i was studied. No enantioselectivity of the transformations of primary-primary 1,6-diols 1a-d to ε-lactones 4a-d was observed. Regioselective oxidation of primary-secondary 1,6-diols 1e,f and 1,5-diols 1h,i afforded enantiomerically enriched ε-lactones 4e,f and δ-lactones 4h,i. ε-Lactones 4e,f were formed with higher enantiomeric excesses (e.e. = 85-99%). Enzymatic oxidation of primary-tertiary 1,6-diol 1g did not give lactone product.

Organoboranr-Catalyzed anti-Markownikoff Hydration of Olefins

A new, catalytic procedure for the anti-Markownikoff hydration of olefins in the presence of organoborane catalyst and dichloroaluminum hydride under dry air has been described.