5309-52-4Relevant articles and documents
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Blanc,P.-Y. et al.
, p. 567 - 575 (1964)
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OXIDATION OF UNSATURATED ALDEHYDES BY PEROXY ACIDS
Pikh, Z. G.,Samarik, V. Ya.
, p. 1294 - 1306 (2007/10/02)
The full composition of the products and the kinetics of their accumulation was studied during the oxidation of a series of unsaturated aldehydes by peroxy acids.The effects of the temperature, the structure of the aldehyde, and the solvent on the reaction rate and quantitative composition of the products were determined.A kinetic model of the reaction is proposed, and its parameters are calculated.New data are obtained on the mechanism of the Baeyer-Villiger reaction as applied to the oxidation of unsaturated aldehydes by peroxy acids.