53112-24-6

Basic information

• Product Name: Benzenesulfenyl bromide, 4-methyl-
• CAS NO: 53112-24-6
• Molecular Formula: C7H7BrS
• Molecular Weight: 203.103
• Mol File: 53112-24-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzenesulfenyl bromide, 4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfenyl bromide, 4-methyl-(53112-24-6)
• EPA Substance Registry System: Benzenesulfenyl bromide, 4-methyl-(53112-24-6)

Safety Data

• Hazardous Substances Data: 53112-24-6(Hazardous Substances Data)

Upstream product

• 2943-42-2 di(4-methyl)phenylthiosulfonate 
• 103-19-5 di(p-tolyl) disulfide 
• 106-45-6 para-thiocresol 

Downstream Products

• 74093-77-9 (Z)-3-Dimethylamino-2-p-tolylsulfanyl-propenal 
• 1950-69-2 toluene-p-sulfonyl bromide 
• 455-16-3 p-toluenesulfonyl fluoride 
• 90584-78-4 ((Z)-3-Dimethylamino-2-p-tolylsulfanyl-allylidene)-dimethyl-ammonium; perchlorate 

Relevant articles and documents

Sulfonyl halide synthesis by thiol oxyhalogenation using NBS/NCS – iPrOH

A rapid and facile method provides a general route to sulfonyl bromides/chlorides by the oxidation of thiols using NXS – ROH (X?=?Br,Cl, R?=?iPr) as an oxyhalogenation reagent. Control experiments suggest that the alcohol component is the source of oxygen. The proposed method enable the access to structurally diverse sulfonyl bromides and chlorides including challenging examples, inaccessible by other synthetic methods.

Highly efficient O-glycosylations with p-tolyl thioribosides and p-TolSOTf

(Chemical Equation Presented) A wide variety of p-tolyl thioriboside donors are examined for O-ribosylations of primary and secondary alcohols. p-Tolylsulfenyl trifluoromethanesulfonate (p-TolSOTf) is very effective in promoting O-ribosylations with p-tol

SULFENYL CHLORIDES, XIV; THE REACTION OF ARYLTHIOSULFONATES WITH ARYLSULFENYL HALIDES

Utilizing partial results published earlier , the sulfenylation reaction of aromatic thiolsulfonates was investigated.Aromatic thiolsulfonates rapidly react with sulfenyl bromide in acetonitrile solution, whereas with sulfenyl chloride the splitting of the thiolsulfonate bond proceeds only in dimethylformamide and under forceful conditions.