53174-37-1

Basic information

• Product Name: N-[1-(4-Nitro-phenyl)-meth-(Z)-ylidene]-N'-(2,3,4,5-tetraphenyl-cyclopenta-2,4-dienylidene)-hydrazine
• CAS NO: 53174-37-1
• Molecular Weight: 531.613
• Mol File: 53174-37-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-[1-(4-Nitro-phenyl)-meth-(Z)-ylidene]-N'-(2,3,4,5-tetraphenyl-cyclopenta-2,4-dienylidene)-hydrazine(CAS DataBase Reference)
• NIST Chemistry Reference: N-[1-(4-Nitro-phenyl)-meth-(Z)-ylidene]-N'-(2,3,4,5-tetraphenyl-cyclopenta-2,4-dienylidene)-hydrazine(53174-37-1)
• EPA Substance Registry System: N-[1-(4-Nitro-phenyl)-meth-(Z)-ylidene]-N'-(2,3,4,5-tetraphenyl-cyclopenta-2,4-dienylidene)-hydrazine(53174-37-1)

Safety Data

• Hazardous Substances Data: 53174-37-1(Hazardous Substances Data)

Upstream product

• 32729-47-8 2,3,4,5-tetraphenylcyclopentadiene hydrazone 
• 555-16-8 4-nitrobenzaldehdye 
• 4828-84-6 diazotetraphenylcyclopentadiene 

Relevant articles and documents

Cyclopentadienylidenephosphinazines

Diazocyclopentadienes which are not alkyl- or aryl-substituted at both the 2- and 5-positions react readily with triphenylphosphine to form cyclopentadienylidenephosphinazines. If both of these positions are so substituted phosphinazines are not formed. A phosphinazine was obtained from 2-chloro-3,4,5-triphenyldiazocyclopentadiene while its 2-nitro-analogue apparently formed a readily hydrolysed phosphinazine. Diazotetraphenylcyclopentadiene formed a phosphinazine with tri-n-butylphosphine. The reasons for these differences in reactivity are discussed. When heated to higher temperatures some of the phosphinazines decomposed with loss of nitrogen to give phosphonium cyclopentadienylides. Electron-withdrawing substituents in the five-membered ring make the phosphinazines susceptible to ready hydrolysis to cyclopentadienone hydrazones. Cyclopentadienylidenephosphinazines are protonated by mineral acids on nitrogen rather than on the cyclopentadiene ring.