5319-41-5Relevant academic research and scientific papers
Tuning chemoselectivity in: O -/ N -arylation of 3-aryl-1,2,4-oxadiazolones with ortho -(trimethylsilyl)phenyl triflates via aryne insertion
Zhou, Lijing,Li, Hongji,Zhang, Wenge,Wang, Lei
supporting information, p. 4822 - 4825 (2018/05/23)
Herein, we first describe finely tunable chemoselectivity in arylation of 3-aryl-1,2,4-oxadiazolones with ortho-(trimethylsilyl)phenyl triflates, including O-arylation enabled by catalytic amount of silver nitrate and metal-free N-arylation. Both the arylation reactions can tolerate a series of functional groups, and afford the corresponding products in moderate to good yields.
