53282-45-4Relevant academic research and scientific papers
Mild Generation of Alkylidenecarbenes from (Tosylazo)alkenes and Silylvinyl Triflates. Mode of Decomposition and Nature of the Carbene Intermediates
Fox, Dennis P.,Bjork, Jon A.,Stang, Peter J.
, p. 3994 - 4002 (2007/10/02)
(Tosylazo)alkenes, R2C=CHN=NTs, decomposed in olefin-solvent mixtures both under neutral conditions at room temperature and with amine bases present to produce alkylidenecyclopropanes in moderate to good yields.Diazoalkenes, R2C=C=N2, were implicated as t
