53282-46-5Relevant academic research and scientific papers
THE EFFECT OF THE TRIFLUOROMETHYL GROUP ON THE METHYLENECYCLOPROPANE REARRANGEMENT
Creary, Xavier,Sky, Anthony F.,Mehrsheikh-Mohammadi, M. E.
, p. 6839 - 6842 (2007/10/02)
The CF3 group, in conjunction with an electron donor group, can enhance the rate of the methylenecyclopropane rearrangement.This is attributed to captodative radical stabilization of the intermediate biradical.
THE EFFECT OF THE DIETHYLPHOSPHONATE GROUP ON FREE RADICAL STABILITIES
Creary, Xavier,Benage, Brigitte,Mehrsheikh-Mohammadi, M. E.,Bays, J. Philip
, p. 2383 - 2386 (2007/10/02)
The diethylphosphonate substituent is free radical stabilizing by a conjugation mechanism as judged by its effect on the rate of the methylenecyclopropane rearrangement.
