5330-25-6

Upstream product

• 1084-96-4 2,5-bis(acetyloxy)benzoic acid 
• 33757-85-6 methyl 2,5-diacetoxybenzoate 
• 3233-32-7 hydroquinone monoacetate 
• 490-79-9 2,5-dihydroxybenzoic acid. 
• 108-24-7 acetic anhydride 

Downstream Products

• 115124-32-8 5-acetoxy-2-hydroxy-benzoic acid ethyl ester 
• 35354-35-9 Methyl-3-chlor-5-acetoxysalicylat 
• 32744-80-2 2-chloro-6-(hydroxymethyl)benzene-1,4-diol 
• 115210-98-5 5-acetoxy-2-(tetra-O-acetyl-β-D-glucopyranosyloxy)-benzoic acid ethyl ester 
• 115486-82-3 5-acetoxy-2-(tetra-O-acetyl-β-D-glucopyranosyloxy)-benzoic acid methyl ester 
• 108975-20-8 2-β-D-glucopyranosyloxy-5-hydroxy-benzoic acid ethyl ester 
• 108124-72-7 2-β-D-glucopyranosyloxy-5-hydroxy-benzoic acid methyl ester 
• 91738-41-9 5-<<2-O-(2,3,5-O-Acetyl-β-D-apiofuranosyl)-3-O-benzyl-4,6-O-benzyliden-β-D-glucopyranosyl>oxy>-2-hydroxybenzoesaeure-methylester 
• 91738-42-0 5-[(2S,3R,4S,5S,6R)-3-((2S,3R,4S)-3,4-Diacetoxy-4-acetoxymethyl-tetrahydro-furan-2-yloxy)-4,5-dihydroxy-6-hydroxymethyl-tetrahydro-pyran-2-yloxy]-2-hydroxy-benzoic acid methyl ester 
• 91738-31-7 2-Benzyloxy-5-<(2,4,6-tri-O-acetyl-3-O-benzyl-β-D-glucopyranosyl)oxy>benzoesaeure-methylester 
• 91738-33-9 5-<(3-O-Benzyl-4,6-O-benzyliden-β-D-glucopyranosyl)oxy>-2-benzyloxybenzoesaeure-methylester 
• 91738-32-8 5-<(3-O-Benzyl-β-D-glucopyranosyl)oxy>-2-benzyloxybenzoesaeure-methylester 
• 67454-60-8 5-<<2-O-(β-D-Apiofuranosyl)-β-D-glucopyranosyl>oxy>-2-hydroxybenzoesaeure 
• 91738-29-3 2-O-Benzyl-5-O-acetylgentisinsaeure-methylester 

Relevant academic research and scientific papers

Cleavage of Carboxylic Esters by Aluminum and Iodine

A one-pot procedure for deprotecting carboxylic esters under nonhydrolytic conditions is described. Typical alkyl carboxylates are readily deblocked to the carboxylic acids by the action of aluminum powder and iodine in anhydrous acetonitrile. Cleavage of lactones affords the corresponding ω-iodoalkylcarboxylic acids. Aryl acetylates undergo deacetylation with the participation of the neighboring group. This method enables the selective cleavage of alkyl carboxylic esters in the presence of aryl esters.

General method for the synthesis of salicylic acids from phenols through palladium-catalyzed silanol-directed C-H carboxylation

A silanol-directed, palladium-catalyzed C-H carboxylation reaction of phenols to give salicylic acids has been developed. This method features high efficiency and selectivity, and excellent functional-group tolerance. The generality of this method was demonstrated by the carboxylation of estrone and by the synthesis of an unsymmetrically o,o′-disubstituted phenolic compound through two sequential C-H functionalization processes.

Synthesis of the First Leaf Movement Factor from Mimosa pudica L.

In the following we describe the synthesis of the first Leaf Movement Factor from Mimosa pudica L.(M-LMF 1).Proceeding from functionalized derivatives of 2,5-dihydroxybenzoic acid (gentisic acid) and D-glucose we obtained by Koenigs-Knorr reaction the pro