5331-38-4Relevant academic research and scientific papers
Allylsulfone compound, method of manufacturing allylsulfone compound, and electrolytic solution for electrochemical device
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Paragraph 0053, (2018/11/22)
PROBLEM TO BE SOLVED: To provide a new sulfone compound useful for an aprotic polar solvent, which is excellent in thermal stability with a relatively low melting point, and has low solubility of water and high decomposition voltage characteristics, and also to provide a method for producing the sulfone compound, and an electrolyte for an electrochemical device which is produced using the sulfone compound.SOLUTION: The sulfone compound is represented by formula (1), wherein R represents 1C-6C alkyl.
A Facile Synthesis of Functionalised Organic Sulphides
Singh, Harjit,Batra, Manohar S.
, p. 1111 - 1112 (2007/10/02)
Thioiminium salts and organic halides or Michael acceptors, in the absence of solvent and at ambient temperature, give title compounds in excellent yields.
Synthesis of Alkenyl Sulphoxides by Intramolecular and Intermolecular Addition of Sulphenic Acids to Alkynes
Bell, Richard,Cottam, Peter D.,Davies, John,Jones, D. Neville
, p. 2106 - 2115 (2007/10/02)
Alkyne-ω-sulphenic acids formed by thermolysis of ω-(t-butylsulphinyl)alkynes at 40 deg C cyclized regiospecifically to 2-methylenethiacycloalkane 1-oxides; 2-methylenethietan 1-oxide was not formed in this way. 2-Methylpropane-2-sulphenic acid, obtained by heating di-t-butyl sulphoxide, added regioselectively to oct-1-yne to give predominantly 2-t-butylsulphinyloct-1-ene, which itself decomposed thermally to a mixture of dioctenyl sulphoxides by way of alkenesulphenic acid-dialkyl sulphine interconversions.Benzenesulphenic acid, methanesulphenic acid, and ethoxycarbonylmethanesulphenic acid, conveniently generated by thermolysis of 1-cyano-2-alkyl(or aryl)sulphinylethanes, underwent intermolecular addition to unactivated and activated alkynes regioselectively to give alkenyl sulphoxides in good yields.
