53317-04-7Relevant academic research and scientific papers
One-dimensional infinite chain organotin complexes: Synthesis and structural characterization of triphenyltin(IV) thiophen-2-carboxylate and triphenyltin(IV) 4-pyridinylcarboxylate
Yin, Handong,Wang, Chuanhua,Wang, Yong,Ma, Chunlin
, p. 48 - 52 (2007/10/03)
Triphenyltin(IV) thiophen-2-carboxylate (1) and triphenyltin(IV) 4-pyridinylcarboxylate (2) have been synthesized by the reaction of sodium 2-thiophenylcarboxylate and sodium 4-pyridinylcarboxylate with the triphenyltin(IV) chloride and characterized by IR, 1H NMR, MS and single crystal X-ray diffraction. In the crystals of 1, the tin atoms are rendered four-coordinated in a distorted tetrahedral structure. Due to the presence of a close intermolecular SnS interaction of 3.339 A, the structure can be described as a weakly-bridged one-dimensional chain polymer. In the crystals of 2, the tin atom is five-coordinated with bridging pyridine N atom and resulting structure is one-dimensional chain polymer.
