53318-08-4

Basic information

• Product Name: Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1R)-
• CAS NO: 53318-08-4
• Molecular Formula: C16H20
• Molecular Weight: 212.335
• Mol File: 53318-08-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1R)-(53318-08-4)
• EPA Substance Registry System: Bicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-(phenylmethyl)-, (1R)-(53318-08-4)

Safety Data

• Hazardous Substances Data: 53318-08-4(Hazardous Substances Data)

Upstream product

• 19894-97-4 (1R)-Myrtenol 
• 55527-89-4 (-)-myrtenyl bromide 
• 591-51-5 phenyllithium 
• 88195-46-4 C₁₆H₂₁NO₃S₂ 
• 108-86-1 bromobenzene 
• 36203-31-3 [(1R,5S)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl]methyl acetate 
• 18172-67-3 beta-pinene 

Relevant articles and documents

Synthesis and reactions of terpenyl diselenides functionalized with phenyl and naphthyl groups

An efficient methodology for the synthesis of chiral terpenyl diselenides functionalized with phenyl and naphthyl groups has been developed. Using the reaction of sodium diselenide with terpenyl tosylates and chlorides, the corresponding diselenides derived from 8-phenyl menthol and isopinocampheol modified at the 10-position were obtained. Diselenides were transformed into electrophilic selenium reagents and tested in the asymmetric selenenylation of styrene. The effect of aryl groups on the enantioselectivity of the addition reaction was examined.

ALKYLATION DE TERPENES EN DEUX ETAPES PAR ENE-REACTION

A simple, two-step homologation of terpenes is reported that requires ene-reaction with PhSO2NSO and subsequent of the intermediate adducts with CuI catalyzed Grignard