53323-72-1

Basic information

• Product Name: [cyclopentadienylFe(CO)₂PF]
• Synonyms: [cyclopentadienylFe(CO)₂PF]
• CAS NO: 53323-72-1
• Molecular Weight: 195.961
• Mol File: 53323-72-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [cyclopentadienylFe(CO)₂PF](CAS DataBase Reference)
• NIST Chemistry Reference: [cyclopentadienylFe(CO)₂PF](53323-72-1)
• EPA Substance Registry System: [cyclopentadienylFe(CO)₂PF](53323-72-1)

Safety Data

• Hazardous Substances Data: 53323-72-1(Hazardous Substances Data)

Downstream Products

• 15318-33-9 trans-carbonyl(chloro)bis(triphenylphosphine)rhodium(I) 
• 71418-10-5 (C₅H₅)Fe(CO)(P(C₆H₅)3)F 

Relevant articles and documents

Formation of phosphorus heterocycles using a cationic electrophilic phosphinidene complex

The electrophilic terminal aminophosphinidene complex [CpFe(CO) 2P{N-i-Pr2}][X] (Cp = cyclopentadienyl, i-Pr = isopropyl, X = AlCl4 or NaBPh4), generated from [CpFe(CO) 2{P(Cl)N-i-Pr2}] by chloride abstraction, reacts with alkynes and alkenes via (1 + 2) cycloaddition to form phosphirenes and phosphiranes respectively. Conjugated alkenes react with [CpFe(CO) 2P{N-i-Pr2}]+ to form phosphirane intermediates, which then rearrange to 3-phospholenes. The phosphinidene complex reacts with benzylideneacetone to give an oxo-3-phospholene complex. Azobenzene reacts with [CpFe(CO)2P{N-i-Pr2}]+ to form a benzodiazophosphole via C-H activation. Addition of HCl or HBF 4·Et2O to the iron diphenylphosphirene complex and iron benzodiazophosphole complex results in P-N bond cleavage, yielding the respective chlorophosphorus heterocyclic complexes. The heterocycles can be removed from the metal complexes to make metal free phosphorus heterocycles by addition of trimethyl- or triethylphosphine.