533903-76-3Relevant academic research and scientific papers
Synthesis of bis(η5-cyclopentadienyldicarbonyliron)stannane dichloride by direct oxidation of tin and reaction of this compound and its analogs with magnesium
Maslennikov,Tsarev,Spirina,Lado,Maslennikov,Usanov
, p. 1101 - 1104 (2007/10/03)
A procedure was developed for preparing [Cp(CO)2Fe] 2SnCl2 by direct oxidation of tin with η5-cyclopentadienyldicarbonyliron chloride in polar solvents. The reaction kinetics was studied, and its scheme was suggested. Products of the reaction of magnesium with compounds R2SnCl2 [R = Cp(CO)3Mo, Cp(CO)3W, Cp(CO)2Fe] were identified. The reaction mechanism was discussed.
