53408-92-7Relevant academic research and scientific papers
Solid-State 199Hg MAS NMR Studies of Mercury(II) Thiocyanate Complexes and Related Compounds. Crystal Structure of Hg(SeCN)2
Bowmaker, Graham A.,Churakov, Andrei V.,Harris, Robin K.,Howard, Judith A. K.,Apperley, David C.
, p. 1734 - 1743 (1998)
The solid-state 199Hg MAS NMR spectra of [Hg(SCN)2], [Hg(SeCN)2], M[Hg(SCN)3), M2[Hg(SCN)4] (M = K, Cs), and K2[Hg3(NCO)8] have been measured, and the (monoclinic) crystal structure of [Hg(SeCN)2] has been determined to assist in the interpretation of the NMR data. The asymmetric unit of Hg(SeCN)2 contains one molecule at an inversion center which shows linear Se-Hg-Se bonding (Hg-Sc = 2.4738(10) ?, Se-Hg-Se = 180°, Hg-Se-C = 97.5(3)°). Secondary Hg-Se and Hg-N contacts are 3.4246(9) and 2.835(12) ?, respectively; this arrangement differs from that in Hg(SCN)2 where there are no secondary Hg-S contacts. A redetermination of the monoclinic crystal structure of K[Hg(SCN)3] is also reported, revealing substantial differences from the earlier work. Spinning sideband analysis has been used to determine the 199Hg shielding anisotropy and asymmetry parameters Δσ and η; from the solid-state 199Hg MAS NMR spectra. The effects of changes in the mercury coordination number and of distortion of the coordination environment on the shielding parameters are interpreted in terms of changes in the local paramagnetic contribution. The same method is employed to assess the effects of secondary bonding on shielding, and it is shown that the substantial differences between the values for Hg(SCN)2 and Hg(SeCN)2 can be attributed to these effects. The ν(HgS) modes have been assigned in the IR and Raman spectra of the thiocyanate complexes, and the correlation between the wavenumbers and splittings of these bands and the 119Hg shielding parameters is discussed.
SYNTHESIS AND STUDIES OF CuHg(NCX)4 (X=S, Se) AND THEIR COMPLEXES AND APPLICATION OF THE SOFTNESS PARAMETER IN THE ELUCIDATION OF THEIR STUCTURE
Singh, P. P.,Pal, R. B.,Srivastava, A. K.
, p. 303 - 316 (2007/10/02)
Complexes of CuHg(NCS)4, CuHg(NCS)2 (NCSe)2 and CuHg(NCSe)4 with tetrahydrofuran, dioxan, pyridine, 2-aminopyridine, nicotinamide, bipyridine and phenanthroline have been prepared and comparative studies made.Bipyridine and phenanthroline form cationic-an
