53423-29-3

Basic information

• Product Name: Benzene, 1-methyl-2-(1-methyl-2-phenylethenyl)-, (E)-
• CAS NO: 53423-29-3
• Molecular Formula: C16H16
• Molecular Weight: 208.303
• Mol File: 53423-29-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methyl-2-(1-methyl-2-phenylethenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methyl-2-(1-methyl-2-phenylethenyl)-, (E)-(53423-29-3)
• EPA Substance Registry System: Benzene, 1-methyl-2-(1-methyl-2-phenylethenyl)-, (E)-(53423-29-3)

Safety Data

• Hazardous Substances Data: 53423-29-3(Hazardous Substances Data)

Upstream product

• 673-32-5 1-Phenylprop-1-yne 
• 16419-60-6 2-Methylphenylboronic acid 
• 932-31-0 ortho-tolylmagnesium bromide 
• 873-66-5 1-propenylbenzene 
• 6699-93-0 (2-methylphenyl)lithium 
• 5033-67-0 2-(2-methylphenyl)-1-phenyl-1-ethanone 
• 644-36-0 o-methylphenylacetic acid 
• 100-44-7 benzyl chloride 
• 17408-14-9 1-(2-(trifluoromethyl)phenyl)ethan-1-one 
• 392-83-6 o-trifluoromethylphenyl bromide 
• 53423-27-1 2-(2-methylphenyl)-1-phenylpropan-1-one 

Relevant articles and documents

Pd-Catalyzed Oxidative Heck Reaction of Grignard Reagents with Diaziridinone as Oxidant

A novel Pd-catalyzed oxidative Heck reaction with readily available Grignard reagents using di-t-butyldiaziridinone as an oxidant has been developed. Various substituted olefins were obtained in 46-91% yields with high regioselectivity under mild reaction conditions.

Palladium-catalyzed hydroarylation of alkynes with arylboronic acids

Reaction of symmetrical and unsymmetrical alkynes with arylboronic acids, using PdCl2 as catalyst source and i-Pr2NPPh2 as ligand, afforded trisubstituted alkenes with regioselectivity in good to excellent yields without a common additional acetic acid. Its efficiency has been demonstrated by its good functional groups, high yield and crowded substrates.