53432-07-8

Upstream product

• 74-96-4 ethyl bromide 
• 1589818-73-4 [Co(PMe₃)₃(C₆HF_{3(meta, meta, para)})-ortho-(CH=N-C₆H₄Cl_para)] 

Downstream Products

• 122519-58-8 {Co(CC-tert-Bu)(CHCH-tert-Bu)(MeCN)(PMe₃)3}BPh₄ 
• 122519-60-2 {Co(CC-n-Pr)(CHCH-n-Pr)(MeCN)(PMe₃)3}BPh₄ 
• 118724-16-6 Co{(C₆H₅)C₂(C₅H₁₁)}{P(CH₃)3}3⁽¹⁺⁾*B(C₆H₅)4^(1-)=Co{(C₆H₅)C₂(C₅H₁₁)}{P(CH₃)3}3B(C₆H₅)4 
• 122519-65-7 {Co(HC₂Ph)(MeCN)(PMe₃)3}BPh₄ 
• 122519-56-6 trimethyl(2-phenyl-2-methoxy-ethyl)phosphonium tetraphenyloborate 
• 122519-62-4 {Co(C₂C₆H₅)2(P(CH₃)3)4}⁽¹⁺⁾*B(C₆H₅)4^(1-) = {Co(C₂C₆H₅)2(P(CH₃)3)4}B(C₆H₅)4 
• 118724-18-8 Co{(C₆H₅)C₂(CH₃)}{P(CH₃)3}3⁽¹⁺⁾*B(C₆H₅)4^(1-)=Co{(C₆H₅)C₂(CH₃)}{P(CH₃)3}3B(C₆H₅)4 
• 83691-46-7 Co{(C₆H₅)C₂(C₆H₅)}{P(CH₃)3}3⁽¹⁺⁾*B(C₆H₅)4^(1-)=Co{(C₆H₅)C₂(C₆H₅)}{P(CH₃)3}3B(C₆H₅)4 
• 122519-63-5 {Co(C₂C₆H₅)2(P(CH₃)3)4}⁽¹⁺⁾*BF₄^(1-) = {Co(C₂C₆H₅)2(P(CH₃)3)4}BF₄ 
• 83691-44-5 (Co(C₂Ph₂)(MeCN)(PMe₃)3)BPh₄ 
• 106468-34-2 [Co(H₂CCH(C₆H₅))(CH₃CN)(P(CH₃)3)3]⁽¹⁺⁾*Br^(1-)=[Co(H₂CCH(C₆H₅))(CH₃CN)(P(CH₃)3)3]Br 
• 104439-74-9 Co((CH₃)4H₂C₄Ge)(P(CH₃)3)3⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Co((CH₃)4H₂C₄Ge)(P(CH₃)3)3]B(C₆H₅)4 
• 104439-72-7 Co((CH₃)4H₂C₄Si)(P(CH₃)3)3⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Co((CH₃)4H₂C₄Si)(P(CH₃)3)3]B(C₆H₅)4 
• 106453-75-2 [Co(H₂CCHCN)(P(CH₃)3)3]⁽¹⁺⁾*B(C₆H₅)4^(1-)=[Co(H₂CCHCN)(P(CH₃)3)3]B(C₆H₅)4 

Relevant academic research and scientific papers

Preparation of organocobalt complexes through CF/CH bond activation of polyfluoroaryl imines

In this paper, we reported the CF and CH bond activation of polyfluoroimine ligands induced by CoMe(PMe3)4. The reaction of pentafluorophenylmethylidene-2,6-diisopropylaniline 1 with CoMe(PMe 3)4 afforded an ortho-chelated cobalt(I) complex [Co(PMe3)3(C6F4-ortho-CH = N-C 6H3(iso-Pr)2(ortho, ortho))] (5) via CF bond activation and subsequent elimination of methyl fluoride. Under similar reaction conditions, the reactions of polyfluoroaryl imines 2-4 with CoMe(PMe 3)4 afforded the penta-coordinate cobalt(I) complexes 6-8 via CH bond activation and subsequent elimination of methane [Co(PMe 3)3(C6H2F 2(meta, meta)-ortho-(CH = N-C6H4Cl para)] (6), [Co(PMe3)3(C6H 2F2(meta, para)-ortho-(CH = N-C6H 4Clpara)] (7), and [Co(PMe3)3(C 6HF3(meta, meta, para)-ortho-(CH = N-C6H 4Clpara)] (8). Complexes 5-8 were characterized through IR, 1H NMR, 31P NMR, 19F NMR and elemental analyses. The crystal and molecular structures of complexes 5, 6 and 8 were determined by X-ray single crystal diffraction. The reactions of 8 with MeI and EtBr afforded organic fluorides 9-10. A proposed formation mechanism of 9-10 with the oxidative addition of RX at the cobalt(I) center of 8 and reductive elimination via C,C-coupling was discussed.