53442-65-2Relevant articles and documents
Photocatalytic Oxygenation Reactions with a Cobalt Porphyrin Complex Using Water as an Oxygen Source and Dioxygen as an Oxidant
Hong, Young Hyun,Han, Ji Won,Jung, Jieun,Nakagawa, Tatsuo,Lee, Yong-Min,Nam, Wonwoo,Fukuzumi, Shunichi
supporting information, p. 9155 - 9159 (2019/06/21)
Photocatalytic oxygenation of hexamethylbenzene occurs under visible-light irradiation of an O2-saturated acetonitrile solution containing a cobalt porphyrin complex CoII(TPP) (TPP2- = tetraphenylporphyrin dianion), water, and triflic acid (HOTf) via a one-photon-two-electron process, affording pentamethylbenzyl alcohol and hydrogen peroxide as products with a turnover number of >6000; in this reaction, H2O and O2 were used as an oxygen source and a two-electron oxidant, respectively. The photocatalytic mechanism was clarified by means of electron paramagnetic resonance, time-resolved fluorescence, and transient absorption measurements as well as 18O-labeling experiments with H218O and 18O2. To the best of our knowledge, we report the first example of efficient photocatalytic oxygenation of an organic substrate by a metal complex using H2O as an oxygen source and O2 as a two-electron oxidant.
Attempts at Direct Detection of Reactive Species in Selective Excitation of the Contact Charge Transfer Pairs of Hexamethylbenzene and Oxygen
Komatsu, Toshiki,Tsuchiya, Masahiro,Furusawa, Gen-ichi,Kuriyama, Yasunao,Sakugari, Hirochika,et al.
, p. 277 - 281 (2007/10/02)
Pulsed laser excitation of contact charge transfer pairs of hexamethylbenzene (HMB) and oxygen in methanol-acetonitrile gave no evidence for intermediacy of reactive species such as HMB radical cations and penthamethylbenzyl cations (ArCH2+), though stationary irradiation of the pair in hydroxylic solvents afforded distinct products arising from the cationic species.The mechanism of reactions was discussed in comparison with 9,10-dicyanoanthracene-sensitized oxygenation of HMB.