53449-07-3Relevant articles and documents
Visible-Light-Mediated Photocatalytic Difunctionalization of Olefins by Radical Acylarylation and Tandem Acylation/Semipinacol Rearrangement
Bergonzini, Giulia,Cassani, Carlo,Lorimer-Olsson, Haldor,H?rberg, Johanna,Wallentin, Carl-Johan
, p. 3292 - 3295 (2016)
A novel method for the mild photoredox-mediated tandem radical acylarylation and tandem acylation/semipinacol rearrangement has been developed. The synthesis of highly functionalized ketones bearing all-carbon α- or β-quaternary centers has been achieved
Catalyst-Dependent Chemoselective Formal Insertion of Diazo Compounds into C?C or C?H Bonds of 1,3-Dicarbonyl Compounds
Liu, Zhaohong,Sivaguru, Paramasivam,Zanoni, Giuseppe,Anderson, Edward A.,Bi, Xihe
supporting information, p. 8927 - 8931 (2018/05/14)
A catalyst-dependent chemoselective one-carbon insertion of diazo compounds into the C?C or C?H bonds of 1,3-dicarbonyl species is reported. In the presence of silver(I) triflate, diazo insertion into the C(=O)?C bond of the 1,3-dicarbonyl substrate leads