53450-79-6

Upstream product

• 13755-29-8 sodium tetrafluoroborate 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 
• 60430-43-5 Rh⁽¹⁺⁾*((C₆H₅)2PCH₂CH₂P(C₆H₅)2)*C₇H₈*BF₄^(1-)={Rh((C₆H₅)2PCH₂CH₂P(C₆H₅)2)(C₇H₈)}BF₄ 

Downstream Products

• 80205-43-2 trans-{Rh(Ph₂PCH₂CH₂PPh₂)2Cl(HgCl)}BF₄ 
• 946090-71-7 Rh(dppe)2 
• 95979-66-1 [Rh((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2]^(1-) 

Relevant academic research and scientific papers

Synthesis and characterization of [Rh(PP)(PP)]X complexes (PP = DPPE or DPPP, X = Cl? or BF4-). Phosphine exchange and reactivity in transfer hydrogenation conditions

The synthesis of heteroleptic monomeric cationic Rh(I) bis-diphosphine complex [Rh(dppe)(dppp)]Cl (dppe = 1,2-bis-(diphenylphosphino)ethane and dppp = 1,3-bis-(diphenylphosphino)propane) was achieved by reaction between the neutral dimeric complex [Rhsub

CATIONIC COMPLEXES OF RHODIUM(I) CATALYSTS IN THE HOMOGENEOUS O2-OXIDATION OF TERMINAL ALKENES TO METHYL KETONES

+, + and + complexes are effective as catalysts for the oxidation by dioxygen of terminal olefins to methyl ketones.The complexes act as monooxygenases, the second oxygen atom being transferred to the alcohol solvent