534568-95-1Relevant academic research and scientific papers
Synthesis and Reactivities of Polyhydrido Osmium Arylsilyl Complexes Prepared from OsH3Cl(PPh3)3
He, Guomei,Wu, Linlin,Bai, Wei,Chen, Jiangxi,Sung, Herman H. Y.,Williams, Ian D.,Lin, Zhenyang,Jia, Guochen
, p. 3729 - 3738 (2017)
Reactions of silanes with transition-metal complexes are of interest because their relevance to Si-H bond activation, the structural properties of polyhydrides, and catalytic hydrosilylation reactions. This work presents the results derived from reactions
Polyhydrido(silylene)osmium and silyl(dinitrogen)ruthenium products through redistribution of phenylsilane with osmium and ruthenium pincer complexes
Gusev, Dmitry G.,Fontaine, Frederic-Georges,Lough, Alan J.,Zargarian, Davit
, p. 216 - 219 (2007/10/03)
Migration/Redistribution Galore! The reaction of phenylsilane with a series of Os and Ru pincer complexes has led to the isolation of complexes 1-3, thus allowing the direct observation of 1,2-addition and redistribution reactions that are so fundamental in the transformations of organosilanes in catalysis. Complex 1 represents a rare example of a complex containing a donor-stabilized SiH2 ligand.
