534568-96-2Relevant academic research and scientific papers
Polyhydrido(silylene)osmium and silyl(dinitrogen)ruthenium products through redistribution of phenylsilane with osmium and ruthenium pincer complexes
Gusev, Dmitry G.,Fontaine, Frederic-Georges,Lough, Alan J.,Zargarian, Davit
, p. 216 - 219 (2003)
Migration/Redistribution Galore! The reaction of phenylsilane with a series of Os and Ru pincer complexes has led to the isolation of complexes 1-3, thus allowing the direct observation of 1,2-addition and redistribution reactions that are so fundamental in the transformations of organosilanes in catalysis. Complex 1 represents a rare example of a complex containing a donor-stabilized SiH2 ligand.
