534584-74-2

Upstream product

• 213777-19-6 (1S,2R,3R,4R)-2-(tert-butyldiphenylsilyloxymethyl)-3-(formylmethyl)-1,4-bis-O-(triethylsilyl)cyclopentane-1,4-diol 
• 502-44-3 hexahydro-2H-oxepin-2-one 
• 4547-43-7 methyl 6-hydroxycaproate 
• 14273-91-7 methyl 6-iodohexanoate 
• 213777-18-5 (1S,2S,3R,4R)-1,4-Bis(triethylsilyloxy)-3-(methoxycarbonylmethyl)-2-tert-butyldiphenylsilyloxymethylcyclopentane 

Downstream Products

• 534584-82-2 (1S,2R,3R,4R)-1,4-di-O-benzoyl-2-(tert-butyldiphenylsilyloxymethyl)-3-[7-(methoxycarbonyl)heptyl]cyclopentane-1,4-diol 
• 534584-98-0 (1S,2S,3R,4R)-1,4-di-O-benzoyl-2-[(1E,3S)-3-hydroxypent-1-enyl]-3-[7-(methoxycarbonyl)heptyl]cyclopentane-1,4-diol 
• 534584-99-1 (1S,2S,3R,4R)-1,4-di-O-benzoyl-2-[(1E,3R)-3-hydroxypent-1-enyl]-3-[7-(methoxycarbonyl)heptyl]cyclopentane-1,4-diol 
• 534584-90-2 (1S,2S,3R,4R)-1,4-di-O-benzoyl-3-[7-(methoxycarbonyl)heptyl]-2-[(E)-3-oxopent-1-enyl]cyclopentane-1,4-diol 
• 534584-86-6 (1S,2R,3R,4R)-1,4-di-O-benzoyl-2-(hydroxymethyl)-3-[7-(methoxycarbonyl)heptyl]cyclopentane-1,4-diol 
• 681449-38-7 C₂₉H₃₄O₇ 
• 534584-78-6 (1S,2R,3R,4R)-2-(tert-butyldiphenylsilyloxymethyl)-3-[7-(methoxycarbonyl)heptyl]cyclopentane-1,4-diol 

Relevant academic research and scientific papers

Total Synthesis of the Eight Diastereomers of the Syn-Anti-Syn Phytoprostanes F1 Types I and II

Syntheses of the eight enantiomerically pure diastereomers of the syn-anti-syn phytoprostanes F1 types I and II are described starting from D- and L-glucose. Key steps include Wittig coupling, Horner Wadsworth Emmons (HWE) reactions, and enantioselective reduction of α,β -unsaturated ketones.

Total synthesis of phytoprostane F1 and its 16 epimer

The first synthesis of the two enantiomers of phytoprostane F1 methyl ester 1 and 2 is described using the syn-anti-syn alcoxy ester 3 as starting material.