53488-14-5Relevant academic research and scientific papers
Highly efficient stereoselective catalytic C(sp3)-H insertions with donor rhodium carbenoids generated from cyclopropenes
Archambeau, Alexis,Miege, Frederic,Meyer, Christophe,Cossy, Janine
, p. 11540 - 11544 (2013/01/15)
Rings of five and six: Donor alkenyl rhodium carbenoids generated from 3,3-dimethylcyclopropenylcarbinols exhibit high reactivity in intramolecular C-H insertions. The reactions proceed under remarkably mild conditions, tolerate the presence of the free hydroxy group, and afford an efficient and stereoselective access to a variety of functionalized carbocycles and oxygen heterocycles. Copyright
NOVEL SYNTHESIS AND APPLICATION OF MIXED ACETALS (ACETYL METHYL ACETALS)
Mandai, Tadakatsu,Irei, Hiroshi,Kawada, Mikio,Otera, Junzo
, p. 2371 - 2374 (2007/10/02)
A novel synthetic method for mixed acetals (acetyl methyl acetals) by electrolysis of hemithioacetals derived from methoxy(phenylthio)methane is newly developed.Synthetic application of these mixed acetals as an aldehyde equivalent is also demonstrated.
