5349-10-0

Basic information

• Product Name: 1,6-Anhydro-2-O,3-O-benzylidene-β-D-mannopyranose
• Synonyms: 1,6-Anhydro-2-O,3-O-benzylidene-β-D-mannopyranose
• CAS NO: 5349-10-0
• Molecular Formula: C₁₃H₁₄O₅
• Molecular Weight: 250.24726
• Mol File: 5349-10-0.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 450.8°C at 760 mmHg
• Flash Point: 226.5°C
• Appearance: /
• Density: 1.371g/cm³
• Vapor Pressure: 6.47E-09mmHg at 25°C
• Refractive Index: 1.581
• CAS DataBase Reference: 1,6-Anhydro-2-O,3-O-benzylidene-β-D-mannopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-Anhydro-2-O,3-O-benzylidene-β-D-mannopyranose(5349-10-0)
• EPA Substance Registry System: 1,6-Anhydro-2-O,3-O-benzylidene-β-D-mannopyranose(5349-10-0)

Safety Data

• Hazardous Substances Data: 5349-10-0(Hazardous Substances Data)

Usage

Chemical compound

A complex chemical compound used in organic synthesis and carbohydrate chemistry.

Derivative of mannose

A derivative of mannose, a naturally occurring sugar.

Glycosidic linkages

Commonly employed in the production of glycosidic linkages.

Benzylidene group

Has a benzylidene group attached to the mannose ring, which imparts unique properties and reactivity to the molecule.

Building block

Often used as a building block in the synthesis of natural products, pharmaceuticals, and other biologically active compounds.

Versatile reagent

The chemical structure makes it a versatile and valuable reagent in the field of organic chemistry.

InChI:InChI=1/C13H14O5/c14-9-8-6-15-13(16-8)11-10(9)17-12(18-11)7-4-2-1-3-5-7/h1-5,8-14H,6H2

Upstream product

• 530-26-7 D-Mannose 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 14168-65-1 mannosan 

Downstream Products

• 145742-75-2 1,6-anhydro-3-O-benzoyl-4-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-β-D-mannopyranose 
• 145742-76-3 1,6-anhydro-2-azido-3-O-benzoyl-2-deoxy-4-O-(2,3,4,6-tetra-O-acetyl-β-D-galactopyranosyl)-β-D-glucopyranose 
• 76752-93-7 1,6-anhydro-2-O-benzoyl-3-desoxy-β-D-arabino-hexopyranose 
• 90662-46-7 8-methoxycarbonyloct-1-yl 4-O-(6-O-acetyl-4-O-allyl-2-O-(6-O-acetyl-2-O-allyl-3,4-di-O-benzoyl-α-D-galactopyranosyl)-3-O-benzyl-β-D-mannopyranosyl)-2,3-O-cyclohexylidene-α-L-rhamnopyranoside 
• 90662-42-3 1,6-di-O-acetyl-4-O-allyl-2-O-(6-O-acetyl-2-O-allyl-3,4-di-O-benzoyl-α-D-galactopyranosyl)-3-O-benzyl-α-D-mannopyranose 
• 90662-43-4 6-O-acetyl-4-O-allyl-2-O-(6-O-acetyl-2-O-allyl-3,4-di-O-benzoyl-α-D-galactopyranosyl)-3-O-benzyl-α-D-mannopyranosyl bromide 
• 90662-41-2 4-O-allyl-2-O-(6-O-acetyl-2-O-allyl-3,4-di-O-benzoyl-α-D-galactopyranosyl)-1,6-anhydro-3-O-benzyl-β-mannopyranose 
• 90662-40-1 4-O-allyl-1,6-anhydro-3-O-benzyl-β-mannopyranose 
• 162710-69-2 O-(2,3,4-Tri-O-benzyl-α-L-fucopyranosyl)-(1->3)-4)>-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose 
• 162710-70-5 O-(2,3,4-Tri-O-benzyl-α-L-fucopyranosyl)-(1->3)-4)>-1,6-anhydro-2-azido-2-deoxy-β-D-glucopyranose 
• 1054657-43-0 Trifluoro-methanesulfonic acid (1R,2S,3S,4S,5R)-2-((2S,3R,4S,5S,6R)-4-allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-3-hydroxy-6,8-dioxa-bicyclo[3.2.1]oct-4-yl ester 
• 162710-67-0 (1R,2S,6S,7R,8R)-7-((2S,3R,4S,5S,6R)-4-Allyloxy-3,5-bis-benzyloxy-6-benzyloxymethyl-tetrahydro-pyran-2-yloxy)-4-phenyl-3,5,10,11-tetraoxa-tricyclo[6.2.1.0^2,6]undecane 

Relevant articles and documents

REACTION OF BUTYLLITHIUM WITH BENZYLIDENE ACETALS OF ALDOPYRANOSIDES AND 1,5-ANHYDROALDITOLS

Under suitable conditions, butyllithium selectively cleaves 5-membered benzylidene acetals (1,3-dioxolane ring) leaving the 6-membered analogs (1,3-dioxane ring) intact in aldopyranoside and 1,5-anhydroalditol derivatives.The usual course of the reaction