53511-09-4Relevant academic research and scientific papers
Synthesis of an [(NHC)2Pd(SiMe3)2] complex and catalytic cis-bis(silyl)ations of alkynes with unactivated disilanes
Ansell, Melvyn B.,Roberts, Debbie E.,Cloke, F. Geoffrey N.,Navarro, Oscar,Spencer, John
, p. 5579 - 5582 (2015)
The novel complex cis-[(ITMe)2Pd(SiMe3)2 (ITMe=1,3,4,5-tetramethylimidazol-2-ylidene) has been synthesized by mild oxidative cleavage of Me3SiSiMe3 using [(ITMe)2Pd0]. The use of this complex as precatalyst for the cis-bis(silyl)ation of alkynes using unactivated disilanes is reported. Double the Si: The novel complex cis-[(ITMe)2Pd(SiMe3)2] (1, ITMe=1,3,4,5-tetramethylimidazol-2-ylidene) has been synthesized by mild oxidative cleavage of Me3SiSiMe3 using [(ITMe)2Pd0]. The synthesized complex was used as a precatalyst for the cis-bis(silyl)ation of alkynes using unactivated disilanes.
