5352-77-2Relevant academic research and scientific papers
Deoxygenation of Unhindered Alcohols via Reductive Dealkylation of Derived Phosphate Esters
Chowdhury, Sarwat,Standaert, Robert F.
, p. 9957 - 9963 (2016/11/02)
Primary alcohols can be deoxygenated cleanly and in yields of 60-95% by reduction of derived diphenyl phosphate esters with lithium triethylborohydride in tetrahydrofuran at room temperature. Selective deoxygenation of a primary alcohol in the presence of a secondary alcohol was demonstrated. The two-step process can be performed in one pot, making it simple and convenient.
TRIS(3,6-DIOXAHEPTYL)AMINE: A SUPERIOR COMPLEXING AGENT FOR DISSOLVING METAL REACTIONS
Bose, Ajay K.,Mangiaracina, Pietro
, p. 2503 - 2506 (2007/10/02)
Commercially available tris(3,6-dioxaheptyl)amine (TDA-1) is an effective phase transfer catalyst for reactions with sodium-potassium alloy in tetrahydrofuran.Deoxygenation of acetates, dehalogenation, and hydrolysis of tosylates and mesylates proceed in high yield.The use of a deuterated alcohol during deoxygenation reactions leads to site-specific deuteration.
