535994-31-1

Basic information

• Product Name: (3S,4R)-3-dimethylphenylsilanyl-4-hydroxy-1,6-heptadiene
• Synonyms: (3S,4R)-3-dimethylphenylsilanyl-4-hydroxy-1,6-heptadiene
• CAS NO: 535994-31-1
• Molecular Weight: 246.425
• Mol File: 535994-31-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (3S,4R)-3-dimethylphenylsilanyl-4-hydroxy-1,6-heptadiene(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R)-3-dimethylphenylsilanyl-4-hydroxy-1,6-heptadiene(535994-31-1)
• EPA Substance Registry System: (3S,4R)-3-dimethylphenylsilanyl-4-hydroxy-1,6-heptadiene(535994-31-1)

Safety Data

• Hazardous Substances Data: 535994-31-1(Hazardous Substances Data)

Upstream product

• 7319-38-2 3-butenal 
• 18001-18-8 allyldimethylphenylsilane 
• 107-18-6 allyl alcohol 
• 327628-40-0 [(E)-γ-(dimethylphenylsilyl)allyl]diisopinocamphenylborane 

Downstream Products

• 611236-32-9 (1R,2S)-2-(dimethylphenylsilanyl)-cyclopent-3-enyl t-butyldimethylsilyl ester 
• 611236-29-4 (3S,4R)-3-dimethylphenylsilyl-hepta-1,6-dien-4-yl t-butyldimethylsilyl ester 

Relevant articles and documents

Asymmetric synthesis of cyclic β-hydroxyallylsilanes via sequential allyltitanation-ring closing metathesis

Highly enantioenriched cyclic β-hydroxyallylsilanes have been prepared via enantioselective allylation of unsaturated aldehydes using a chiral allyltitanium reagent, followed by a ring-closing metathesis. Functionalized rings of various sizes have been sy

Enantio- and diastereoselective synthesis of cyclic β-hydroxy allylsilanes via sequential aldehyde γ-silylallylboration and ring-closing metathesis reactions

(Matrix presented) Highly enantioenriched cyclic allylsilanes are prepared via stereoselective γ-silylallylboration reactions of β- or γ-unsaturated aldehydes followed by ring-closing metathesis.