535994-48-0Relevant academic research and scientific papers
Stereoselective synthesis of a monocyclic peloruside A analogue
Wulischleger, Christoph W.,Gertsch, Juerg,Altmann, Karl-Heinz
supporting information; experimental part, p. 1120 - 1123 (2010/06/13)
Chemical Equation Presentation The stereoselective synthesis of the monocyclic peloruside A analogue 4 has been achieved, following a new efficient approach for the introduction of the side chain, involving a late-stage addition of vinyl lithium species 7a to aldehyde 8. Further key steps are a highly diastereoselective allyltitanation reaction and a RCM-based macrocyclization.
Enantio- and diastereoselective synthesis of cyclic β-hydroxy allylsilanes via sequential aldehyde γ-silylallylboration and ring-closing metathesis reactions
Heo, Jung-Nyoung,Micalizio, Glenn C.,Roush, William R.
, p. 1693 - 1696 (2007/10/03)
(Matrix presented) Highly enantioenriched cyclic allylsilanes are prepared via stereoselective γ-silylallylboration reactions of β- or γ-unsaturated aldehydes followed by ring-closing metathesis.
