53602-02-1Relevant academic research and scientific papers
Synthetic Photochemistry: Synthesis of (+/-)-Oliveridine
Kessar, S. V.,Mohammad, Taj,Gupta, Y. P.
, p. 321 - 324 (2007/10/02)
The first synthesis of (+/-)-oliveridine (9b) and (+/-)-epioliveridine (9a) are described.The key steps are:(i) preparation of N--2'-bromo-5'-methoxyphenylacetamide (4), its Bischler-Napieralski cyclisation followed by m
Photocyclisation of 1-(2'-Halo-α-hydroxybenzyl)-1,2,3,4-tetrahydroisoquinolines; Synthesis of (+/-)-Oliveridine
Kessar, S. V.,Gupta, Y. P.,Mohammad, Taj
, p. 984 (2007/10/02)
In contrast to α-deoxy analogs, photocyclisation of 1-(2'-halo-α-hydroxybenzyl)-1,2,3,4-tetrahydroisoquinolines to aporphines succeeds even in cyclohexane solvent, probably because of internal hydrogen bonding.A synthesis of the alkaloid oliveridine is de
