53603-22-8

Upstream product

• 675-10-5 4-hydroxy-6-methyl-2-pyron 
• 1142-19-4 4,4'-dichlorodiphenyl disulfide 
• 28823-18-9 S-(4-chlorophenyl) 4-methylbenzenesulfonothioate 
• 30536-52-8 sodium salt of triacetic acid lactone 

Relevant academic research and scientific papers

Sulfenylation of heterocyclic 1,3-dicarbonyl systems: 4-Hydroxy-2-pyrones, 6-hydroxy-4-pyrimidones, 4-hydroxy-2-pyridones, 4-hydroxy-6-pyridazinones, and 5-hydroxy-3-pyrazolones

Anions of enolized heteroaromatic 1,3-dicarbonyl systems, such as the title compounds 1, 9, 14, and 19, react in dimethylformamide in the presence of potassium carbonate with diaryl disulfides 2 to yield arylsulfenyl derivatives (3, 10, 15, 20). The arylt

Process for preparing sulfur-containing hydroxy pyrones

This invention concerns sulfur-containing hydroxy pyrones corresponding to the formula SPC1 Wherein M is H or alkali metal, R is methyl, R' is hydrogen, alkyl, phenyl, halophenyl, nitrophenyl, loweralkylphenyl, benzyl, phenethyl, naphthylmethyl, halobenzyl, loweralkylbenzyl, nitrobenzyl, propargyl, allyl, cyclohexyl loweralkyl, (loweralkylthio)-loweralkyl or adamantyl and n is 0 to 2. The compounds are prepared by reacting the mono-alkali metal salt of 4-hydroxy-6-methyl-2-pyrone with an appropriate thiosulfonate, advantageously in the presence of an organic solvent. The compounds have utility as plant growth stunters and as antimicrobial agents.